Reaction
ChemicalBook > CAS DataBase List > 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl

2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl

Reaction
Product Name
2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl
CAS No.
1262046-34-3
Chemical Name
2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl
Synonyms
Rockphos;Di-tert-butyl(2′,4′,6′-triisopropyl-3-methoxy-6-methyl-[1,1′-biphenyl]-2-yl)phosphine;Rockpahos;RockPhos 97%;Bis(1,1-dimethylethyl)[3-me;2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2',4',6'-triisopro;2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2'-4'-6'-triisopropylbiphenyl;2-Di(tert-butyl)phosphino-2′,4′,6′-triisopropyl-3-methoxy-6-methylbiphenyl;Di-tert-butyl(2',4',6'-triisopropyl-3-methoxy-6-methyl-2-biphenylyl)phosphine;ditert-butyl-[6-methoxy-3-methyl-2-(2,4,6-triisopropylphenyl)phenyl]phosphane
CBNumber
CB12642764
Molecular Formula
C31H49OP
Formula Weight
468.69
MOL File
1262046-34-3.mol
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2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl Property

Melting point:
129-130°C
Boiling point:
526.6±50.0 °C(Predicted)
storage temp. 
15-25°C
form 
crystal
color 
white
CAS DataBase Reference
1262046-34-3
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Safety

WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
791016
Product name
2-Di(tert-butyl)phosphino-2′,4′,6′-triisopropyl-3-methoxy-6-methylbiphenyl
Purity
97%
Packaging
500mg
Price
$599
Updated
2024/03/01
Sigma-Aldrich
Product number
791016
Product name
2-Di(tert-butyl)phosphino-2′,4′,6′-triisopropyl-3-methoxy-6-methylbiphenyl
Purity
97%
Packaging
2g
Price
$1340
Updated
2024/03/01
Strem Chemicals
Product number
15-1168
Product name
2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl, min. 98% RockPhos
Packaging
100mg
Price
$125
Updated
2024/03/01
Strem Chemicals
Product number
15-1168
Product name
2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl, min. 98% RockPhos
Packaging
500mg
Price
$499
Updated
2024/03/01
Strem Chemicals
Product number
15-1168
Product name
2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl, min. 98% RockPhos
Packaging
2g
Price
$1288
Updated
2024/03/01
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2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl Chemical Properties,Usage,Production

Reaction

Ligand used in the palladium-catalyzed C-O bond forming reactions of secondary and primary alcohols with a range of aryl halides. Heterocyclic halides and, for the first time, electron-rich aryl halides can be coupled with secondary alcohols.

Uses

Rockpahos is commonly used as a catalyst in organic reactions along with a palladium compound catalyst.

Uses

RockPhos is a biphenyl-based phosphine ligand used with Pd(0) catalyst for carbon-carbon and carbon-heteroatom bond formation reactions.
It can also be employed in the:

  • 2-fluroethoxylation of bromo-chalcones in the presence of palladium catalyst.
  • Conversion of aryl chlorides into aryl methoxides using RockPhos Pd G3 as a catalyst.

2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl Suppliers

Aladdin Scientific
Tel
+1-833-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57511
Advantage
58
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View Lastest Price from 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl manufacturers

Speranza Chemical Co., Ltd.
Product
2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl 1262046-34-3
Price
US $0.00-0.00/KG
Min. Order
5KG
Purity
98%
Supply Ability
25KG
Release date
2024-01-05
Shaanxi Dideu Medichem Co. Ltd
Product
2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2'-4'-6'-triisopropylbiphenyl 1262046-34-3
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2020-01-16

1262046-34-3, 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenylRelated Search:


  • Rockphos
  • 2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2'-4'-6'-triisopropylbiphenyl, 98% Min
  • 2-(Di-t-butylphosphino)-3-Methoxy-6-Methyl-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, Min. 98% RockPhos
  • Bis(1,1-dimethylethyl)[3-methoxy-6-methyl-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine
  • 2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2',4',6'-triisopropyl-1,1'-biphenyl
  • Di-tert-butyl(2′,4′,6′-triisopropyl-3-methoxy-6-methyl-[1,1′-biphenyl]-2-yl)phosphine
  • RockPhos 97%
  • 2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2'-4'-6'-triisopropylbiphenyl
  • 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl
  • 2-Di(tert-butyl)phosphino-2′,4′,6′-triisopropyl-3-methoxy-6-methylbiphenyl
  • 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl, RockPhos
  • Bis(1,1-dimethylethyl)[3-me
  • 2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2',4',6'-triisopro
  • Di-tert-butyl(2',4',6'-triisopropyl-3-methoxy-6-methyl-[1,1'-biphenyl]-2-yl)phosphane
  • 2-Di-tert-butylphosphino-3- Methoxy-6-Methyl-2,4',6'- triisopropylbiphenyl (Rockphos)
  • ditert-butyl-[6-methoxy-3-methyl-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane
  • Phosphine, bis(1,1-dimethylethyl)[3-methoxy-6-methyl-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]-
  • Rockpahos
  • Di-tert-butyl(2',4',6'-triisopropyl-3-methoxy-6-methyl-2-biphenylyl)phosphine
  • 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propylbiphenyl (Rockphos)
  • 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl
  • Di-tert-butyl(2',4',6'-triisopropyl-3-methoxy-6-methyl-[1,1'-biphenyl]-2-yl)phosphine
  • ditert-butyl-[6-methoxy-3-methyl-2-(2,4,6-triisopropylphenyl)phenyl]phosphane
  • 1262046-34-3
  • 1260246-34-3
  • C31H49OP
  • Achiral Phosphine
  • Aryl Phosphine
  • Buchwald Ligands Series
  • Buchwald Ligands&Precatalysts